KRISTALINITAS DAN UJI ADSORPSI KOMPLEKS KITOSAN TEMBAGA (II) PADA ZAT WARNA KONGO MERAH
Abstract
Penelitian tentang adsorpsi zat warna kongo merah telah dilakukan dengan tujuan untuk mengetahui kemampuan adsorpsi kitosan setelah dimodifikasi dengan tembaga (II) (CNC) dalam menurunkan kadar zat warna dan untuk mengetahui kondisi optimum dari penyerap terhadap penurunan kadar zat warna kongo merah. Modifikasi kitosan-tembaga (II) dilakukan dengan menggunakan metode kopresipitasi. Karakterisasi kristalinitas ditentukan secara difraksi sinar-X. Proses adsorpsi dilakukan dengan metode Bacth meliputi variasi pH. Analisis terhadap adsorpsi Kongo merah menggunakan spektrofotometer Ultraviolet-Visible. Hasil penelitian menunjukkan bahwa kitosan-tembaga (II) mampu menurunkan kadar zat warna kongo merah hingga 95,8% sedangkan kitosan hanya mencapai 72,3%. Kondisi optimum adsorpsi zat warna Kongo merah oleh kitosan dan kitosan-tembaga (II) terjadi pada pH 5.
References
Adebayo, M. A., Jabar, J. M., Amoko, J. S., Openiyi, E. O., & Shodiya, O. O. (2022). Coconut HuskzRaw Clay-Fe Composite: Preparation, Characteristics and Mechanisms of Congo Red Adsorption. Scientific Reports. https://doi.org/10.1038/s41598-022-18763-y
Aldila, H. (2021). Ekstraksi Kitosan Dari Limbah Cangkang Udang Sebagai Adsorben Ion Logam Cu Pada Air Kolong Timah Bangka. Promine. https://doi.org/10.33019/promine.v8i2.2070
Bandura, L., Franus, M., Madej, J., Kołodyńska, D., & Hubicki, Z. (2020). Zeolites in Phenol Removal in the Presence of Cu(II) Ions—Comparison of Sorption Properties After Chitosan Modification. Materials. https://doi.org/10.3390/ma13030643
Bhatlu, M. L. D., Athira, P. S., Jayan, N., Barik, D., & Dennison, M. S. (2023). Preparation of Breadfruit Leaf Biochar for the Application of Congo Red Dye Removal From Aqueous Solution and Optimization of Factors by RSM-BBD. Adsorption Science & Technology. https://doi.org/10.1155/2023/7369027
Bulgariu, L., Escudero, L. B., Bello, O. S., Iqbal, M., Nisar, J., Adegoke, K. A., Alakhras, F., Kornaros, M., & Anastopoulos, I. (2019). The Utilization of Leaf-Based Adsorbents for Dyes Removal: A Review. Journal of Molecular Liquids. https://doi.org/10.1016/j.molliq.2018.12.001
Fortuna, F., & Rasikarahma, R. (2022). Autologous Fat Grafting on the Right Leg : Sebuah Laporan Kasus. Scientific Journal. https://doi.org/10.56260/sciena.v1i5.74
Gritsch, L., Lovell, C., Goldmann, W. H., & Boccaccini, A. R. (2018). Fabrication and Characterization of Copper(II)-Chitosan Complexes as Antibiotic-Free Antibacterial Biomaterial. Carbohydrate Polymers. https://doi.org/10.1016/j.carbpol.2017.09.095
Gritsch, L., Maqbool, M., Mouriño, V., Ciraldo, F. E., Cresswell, M., Jackson, P., Lovell, C., & Boccaccini, A. R. (2019). Chitosan/Hydroxyapatite Composite Bone Tissue Engineering Scaffolds With Dual and Decoupled Therapeutic Ion Delivery: Copper and Strontium. Journal of Materials Chemistry B. https://doi.org/10.1039/c9tb00897g
Gu, G., Erişen, D. E., Yang, K., Zhang, B., Shen, M., Zou, J., Qi, X., Chen, S., & Xu, X. (2022). Antibacterial andanti‐inflammatory Activities of Chitosan/Copper Complex Coating on Medical Catheters: In Vitro and in Vivo. Journal of Biomedical Materials Research Part B Applied Biomaterials. https://doi.org/10.1002/jbm.b.35047
Kalantaryan, M., Abrahamyan, G., & Hoveyan, H. A. (2022). Anionic Dye Removal From Aqueous Solution Using Chitosan Modified Irind Mine Pumice. Journal of Architectural and Engineering Research. https://doi.org/10.54338/27382656-2022.2-006
Lafi, R., Montasser, I., & Hafiane, A. (2018). Adsorption of Congo Red Dye From Aqueous Solutions by Prepared Activated Carbon With Oxygen-Containing Functional Groups and Its Regeneration. Adsorption Science & Technology. https://doi.org/10.1177/0263617418819227
Leswana, N. F., Siswanta, D., & Suratman, A. (2021). Synthesis Polyelectrolyte Complex Membrane Polystyrene Sufonate-Chitosan From Styrofoam Waste as the Adsorbent for Cu(II) and Ni(II) Metal. Jurnal Farmasi Etam (Jfe). https://doi.org/10.52841/jfe.v1i1.173
Li, F., Liu, Y., Li, Z., Li, Q., Li, X., & Cui, H. (2019). Cu(II)-Regulated on-Site Assembly of Highly Chemiluminescent Multifunctionalized Carbon Nanotubes for Inorganic Pyrophosphatase Activity Determination. Acs Applied Materials & Interfaces. https://doi.org/10.1021/acsami.9b20259
Liu, J., Liu, S., Wu, Q., Gu, Y., Kan, J., & Jin, C. (2017). Effect of protocatechuic acid incorporation on the physical, mechanical, structural and antioxidant properties of chitosan film. Food Hydrocolloids, 73, 90–100.
Liu, Y., Qiu, G., Li, T., Yan, A., Liu, Y., Qu, R., & Sun, C. (2021). Preparation of Metal Organic Framework Hybridizing With Poly(p-Phenylene Terephthalamide) Fiber and Adsorption Properties for Anionic Dye. Pigment & Resin Technology. https://doi.org/10.1108/prt-08-2021-0092
Marković, D., Zille, A., Ribeiro, A. I., Mikučionienė, D., Simončič, B., Tomšič, B., & Radetić, M. (2022). Antibacterial Bio-Nanocomposite Textile Material Produced From Natural Resources. Nanomaterials. https://doi.org/10.3390/nano12152539
Mutakhabbibatillah, M. (2023). Efektivitas Koagulan Kitosan Pada Pengolahan Air Di Unit Water Treatment PPSDM Migas Cepu. Distilat Jurnal Teknologi Separasi. https://doi.org/10.33795/distilat.v8i3.396
Nasution, M. S. K. (2022). Peranan Senyawa Kompleks Dalam Bidang Medis: Literatur Studi. Jurnal Impresi Indonesia. https://doi.org/10.36418/jii.v1i5.64
Nguyen, N. T., Nguyen, N. T., & Nguyen, V. A. (2020). In Situ Synthesis and Characterization of ZnO/Chitosan Nanocomposite as an Adsorbent for Removal of Congo Red From Aqueous Solution. Advances in Polymer Technology. https://doi.org/10.1155/2020/3892694
Omar, F. A., El-Tonsy, M. M., Oraby, A. H., & Reicha, F. M. (2023). Copper and Copper Oxides Nanoparticles Synthesized by Electrochemical Technique in Chitosan Solution. International Journal of Science and Engineering Applications. https://doi.org/10.7753/ijsea0503.1009
Osarumwense, J. O., Akpaja, E. O., & Ekhosuehi, J. A. (2018). Preparation and Characterisation of Chitosan From ≪i>Penicillium Chrysogenum</I> Thom for Decolourisation of Congo Red Dye in Aqueous Solution. Journal of Applied Sciences and Environmental Management. https://doi.org/10.4314/jasem.v21i7.26
Pathirana, M. A., Dissanayake, N. S. L., Wanasekara, N. D., Mahltig, B., & Nandasiri, G. K. (2023). Chitosan-Graphene Oxide Dip-Coated Polyacrylonitrile-Ethylenediamine Electrospun Nanofiber Membrane for Removal of the Dye Stuffs Methylene Blue and Congo Red. Nanomaterials. https://doi.org/10.3390/nano13030498
Ramadhani, P., Chaidir, Z., Zilfa, Z., Fauzia, S., & Zein, R. (2021). Isolation of chitosan from shrimp shell (Metapenaeus monoceros) as adsorbent for removal of metanil yellow dyes. Journal of the Iranian Chemical Society, 1–15.
Rehman, R., Waheed-uz-Zaman, Raza, A., Noor, W., Batool, A., & Maryem, H. (2021). Photocatalytic Degradation of Alizarin Red S, Amaranth, Congo Red, and Rhodamine B Dyes Using UV Light Modified Reactor and ZnO, TiO2, and SnO2 as Catalyst. Journal of Chemistry. https://doi.org/10.1155/2021/6655070
Silalahi, I. H., Julan, J., Yusprianto, M., & Rudiyansyah. (2021). Sintesis Dan Transisi Elektronik Kompleks Tembaga (Ii)-Klorofil. Indonesian Journal of Pure and Applied Chemistry. https://doi.org/10.26418/indonesian.v3i3.44149
Thanh, N. N., Tung, N. T., Nguyen, V. A., Chung, N. T., & Thinh, N. A. (2022). Removal of Congo Red Dye From Aqueous Solution Using Nano ZnO/chitosan Composite. Vietnam Journal of Catalysis and Adsorption. https://doi.org/10.51316/jca.2022.070
Vahidhabanu, S., Adeogun, A. I., & Babu, B. R. (2019). Biopolymer-Grafted, Magnetically Tuned Halloysite Nanotubes as Efficient and Recyclable Spongelike Adsorbents for Anionic Azo Dye Removal. Acs Omega. https://doi.org/10.1021/acsomega.8b02960
Varma, R., & Vasudevan, S. (2020). Extraction, characterization, and antimicrobial activity of chitosan from horse mussel modiolus modiolus. ACS Omega, 5(32), 20224–20230.
Xiao, Y., Shen, G., Zheng, W., Fu, J., Fu, F., Hu, X., Jin, Z., & Liu, X. (2022). Remarkable Durability of the Antibacterial Function Achieved via a Coordination Effect of Cu(II) Ion and Chitosan Grafted on Cotton Fibers. Cellulose. https://doi.org/10.1007/s10570-021-04281-z
Zainudin, N. F., Sam, S. T., Wong, Y.-S., Ismail, H., Walli, S., Inoue, K., Kawamura, G., & Tan, W. (2023). Degradation of Diazo Congo Red Dye by Using Synthesized Poly-Ferric-Silicate-Sulphate Through Co-Polymerization Process. Polymers. https://doi.org/10.3390/polym15010237
Aldila, H. (2021). Ekstraksi Kitosan Dari Limbah Cangkang Udang Sebagai Adsorben Ion Logam Cu Pada Air Kolong Timah Bangka. Promine. https://doi.org/10.33019/promine.v8i2.2070
Bandura, L., Franus, M., Madej, J., Kołodyńska, D., & Hubicki, Z. (2020). Zeolites in Phenol Removal in the Presence of Cu(II) Ions—Comparison of Sorption Properties After Chitosan Modification. Materials. https://doi.org/10.3390/ma13030643
Bhatlu, M. L. D., Athira, P. S., Jayan, N., Barik, D., & Dennison, M. S. (2023). Preparation of Breadfruit Leaf Biochar for the Application of Congo Red Dye Removal From Aqueous Solution and Optimization of Factors by RSM-BBD. Adsorption Science & Technology. https://doi.org/10.1155/2023/7369027
Bulgariu, L., Escudero, L. B., Bello, O. S., Iqbal, M., Nisar, J., Adegoke, K. A., Alakhras, F., Kornaros, M., & Anastopoulos, I. (2019). The Utilization of Leaf-Based Adsorbents for Dyes Removal: A Review. Journal of Molecular Liquids. https://doi.org/10.1016/j.molliq.2018.12.001
Fortuna, F., & Rasikarahma, R. (2022). Autologous Fat Grafting on the Right Leg : Sebuah Laporan Kasus. Scientific Journal. https://doi.org/10.56260/sciena.v1i5.74
Gritsch, L., Lovell, C., Goldmann, W. H., & Boccaccini, A. R. (2018). Fabrication and Characterization of Copper(II)-Chitosan Complexes as Antibiotic-Free Antibacterial Biomaterial. Carbohydrate Polymers. https://doi.org/10.1016/j.carbpol.2017.09.095
Gritsch, L., Maqbool, M., Mouriño, V., Ciraldo, F. E., Cresswell, M., Jackson, P., Lovell, C., & Boccaccini, A. R. (2019). Chitosan/Hydroxyapatite Composite Bone Tissue Engineering Scaffolds With Dual and Decoupled Therapeutic Ion Delivery: Copper and Strontium. Journal of Materials Chemistry B. https://doi.org/10.1039/c9tb00897g
Gu, G., Erişen, D. E., Yang, K., Zhang, B., Shen, M., Zou, J., Qi, X., Chen, S., & Xu, X. (2022). Antibacterial and
Kalantaryan, M., Abrahamyan, G., & Hoveyan, H. A. (2022). Anionic Dye Removal From Aqueous Solution Using Chitosan Modified Irind Mine Pumice. Journal of Architectural and Engineering Research. https://doi.org/10.54338/27382656-2022.2-006
Lafi, R., Montasser, I., & Hafiane, A. (2018). Adsorption of Congo Red Dye From Aqueous Solutions by Prepared Activated Carbon With Oxygen-Containing Functional Groups and Its Regeneration. Adsorption Science & Technology. https://doi.org/10.1177/0263617418819227
Leswana, N. F., Siswanta, D., & Suratman, A. (2021). Synthesis Polyelectrolyte Complex Membrane Polystyrene Sufonate-Chitosan From Styrofoam Waste as the Adsorbent for Cu(II) and Ni(II) Metal. Jurnal Farmasi Etam (Jfe). https://doi.org/10.52841/jfe.v1i1.173
Li, F., Liu, Y., Li, Z., Li, Q., Li, X., & Cui, H. (2019). Cu(II)-Regulated on-Site Assembly of Highly Chemiluminescent Multifunctionalized Carbon Nanotubes for Inorganic Pyrophosphatase Activity Determination. Acs Applied Materials & Interfaces. https://doi.org/10.1021/acsami.9b20259
Liu, J., Liu, S., Wu, Q., Gu, Y., Kan, J., & Jin, C. (2017). Effect of protocatechuic acid incorporation on the physical, mechanical, structural and antioxidant properties of chitosan film. Food Hydrocolloids, 73, 90–100.
Liu, Y., Qiu, G., Li, T., Yan, A., Liu, Y., Qu, R., & Sun, C. (2021). Preparation of Metal Organic Framework Hybridizing With Poly(p-Phenylene Terephthalamide) Fiber and Adsorption Properties for Anionic Dye. Pigment & Resin Technology. https://doi.org/10.1108/prt-08-2021-0092
Marković, D., Zille, A., Ribeiro, A. I., Mikučionienė, D., Simončič, B., Tomšič, B., & Radetić, M. (2022). Antibacterial Bio-Nanocomposite Textile Material Produced From Natural Resources. Nanomaterials. https://doi.org/10.3390/nano12152539
Mutakhabbibatillah, M. (2023). Efektivitas Koagulan Kitosan Pada Pengolahan Air Di Unit Water Treatment PPSDM Migas Cepu. Distilat Jurnal Teknologi Separasi. https://doi.org/10.33795/distilat.v8i3.396
Nasution, M. S. K. (2022). Peranan Senyawa Kompleks Dalam Bidang Medis: Literatur Studi. Jurnal Impresi Indonesia. https://doi.org/10.36418/jii.v1i5.64
Nguyen, N. T., Nguyen, N. T., & Nguyen, V. A. (2020). In Situ Synthesis and Characterization of ZnO/Chitosan Nanocomposite as an Adsorbent for Removal of Congo Red From Aqueous Solution. Advances in Polymer Technology. https://doi.org/10.1155/2020/3892694
Omar, F. A., El-Tonsy, M. M., Oraby, A. H., & Reicha, F. M. (2023). Copper and Copper Oxides Nanoparticles Synthesized by Electrochemical Technique in Chitosan Solution. International Journal of Science and Engineering Applications. https://doi.org/10.7753/ijsea0503.1009
Osarumwense, J. O., Akpaja, E. O., & Ekhosuehi, J. A. (2018). Preparation and Characterisation of Chitosan From ≪i>Penicillium Chrysogenum</I> Thom for Decolourisation of Congo Red Dye in Aqueous Solution. Journal of Applied Sciences and Environmental Management. https://doi.org/10.4314/jasem.v21i7.26
Pathirana, M. A., Dissanayake, N. S. L., Wanasekara, N. D., Mahltig, B., & Nandasiri, G. K. (2023). Chitosan-Graphene Oxide Dip-Coated Polyacrylonitrile-Ethylenediamine Electrospun Nanofiber Membrane for Removal of the Dye Stuffs Methylene Blue and Congo Red. Nanomaterials. https://doi.org/10.3390/nano13030498
Ramadhani, P., Chaidir, Z., Zilfa, Z., Fauzia, S., & Zein, R. (2021). Isolation of chitosan from shrimp shell (Metapenaeus monoceros) as adsorbent for removal of metanil yellow dyes. Journal of the Iranian Chemical Society, 1–15.
Rehman, R., Waheed-uz-Zaman, Raza, A., Noor, W., Batool, A., & Maryem, H. (2021). Photocatalytic Degradation of Alizarin Red S, Amaranth, Congo Red, and Rhodamine B Dyes Using UV Light Modified Reactor and ZnO, TiO2, and SnO2 as Catalyst. Journal of Chemistry. https://doi.org/10.1155/2021/6655070
Silalahi, I. H., Julan, J., Yusprianto, M., & Rudiyansyah. (2021). Sintesis Dan Transisi Elektronik Kompleks Tembaga (Ii)-Klorofil. Indonesian Journal of Pure and Applied Chemistry. https://doi.org/10.26418/indonesian.v3i3.44149
Thanh, N. N., Tung, N. T., Nguyen, V. A., Chung, N. T., & Thinh, N. A. (2022). Removal of Congo Red Dye From Aqueous Solution Using Nano ZnO/chitosan Composite. Vietnam Journal of Catalysis and Adsorption. https://doi.org/10.51316/jca.2022.070
Vahidhabanu, S., Adeogun, A. I., & Babu, B. R. (2019). Biopolymer-Grafted, Magnetically Tuned Halloysite Nanotubes as Efficient and Recyclable Spongelike Adsorbents for Anionic Azo Dye Removal. Acs Omega. https://doi.org/10.1021/acsomega.8b02960
Varma, R., & Vasudevan, S. (2020). Extraction, characterization, and antimicrobial activity of chitosan from horse mussel modiolus modiolus. ACS Omega, 5(32), 20224–20230.
Xiao, Y., Shen, G., Zheng, W., Fu, J., Fu, F., Hu, X., Jin, Z., & Liu, X. (2022). Remarkable Durability of the Antibacterial Function Achieved via a Coordination Effect of Cu(II) Ion and Chitosan Grafted on Cotton Fibers. Cellulose. https://doi.org/10.1007/s10570-021-04281-z
Zainudin, N. F., Sam, S. T., Wong, Y.-S., Ismail, H., Walli, S., Inoue, K., Kawamura, G., & Tan, W. (2023). Degradation of Diazo Congo Red Dye by Using Synthesized Poly-Ferric-Silicate-Sulphate Through Co-Polymerization Process. Polymers. https://doi.org/10.3390/polym15010237
Published
2024-01-29
How to Cite
RIAPANITRA, Anung et al.
KRISTALINITAS DAN UJI ADSORPSI KOMPLEKS KITOSAN TEMBAGA (II) PADA ZAT WARNA KONGO MERAH.
Prosiding Seminar Nasonal LPPM UNSOED, [S.l.], v. 13, n. 1, p. 62-70, jan. 2024.
ISSN 2985-9042.
Available at: <http://jos.unsoed.ac.id/index.php/semnaslppm/article/view/10308>. Date accessed: 30 apr. 2024.
doi: https://doi.org/10.20884/1.semnaslppm.2024.13.1.10308.
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Articles
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